Illustration of dark crystalline seleniumSELENIUM / ILLUSTRATION

01 Rare materials

Selenium.

An uncommon element with distinctive properties. Grey selenium responds electrically to light and has a place in several industrial processes.

Chemically, selenium is a non-metal. In this range it sits alongside rare technical materials. Purity, form and composition determine the right grade for a specific application.

SeAtomic number 34Group 16
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02 The material

Small in quantity.
Big in function.

Selenium occurs naturally in small amounts and often accompanies sulfur-bearing ores. Industrial production commonly recovers it as a by-product of copper refining. Depending on its structure, it may appear red, black or metallic grey. The grey crystalline form is the most stable.

Its photoconductivity is particularly distinctive: light changes the electrical conductivity of grey selenium. This property made it useful in photoelectric cells and traditional copying technology. Applications also include special glass, ceramic pigments and selected metallurgical additives.

Important for sourcingThese properties describe the element in general. Supply grade and availability are assessed against your specification.

03 Material data

Technical
information.

Indicative values for elemental grey selenium. Agreed product documents govern any delivery.

Symbol
Se
Atomic number
34
Relative atomic mass
78.971
Element group
16 · Chalcogens
Density
approx. 4.81 g/cm³
Melting point
approx. 220.8 °C
Boiling point
approx. 685 °C
Purity / form
On request

Reference values: Royal Society of Chemistry. Values may vary by allotrope and measurement conditions.

04 Applications

One element.
Many functions.

The application shapes requirements for purity, particle size and composition. Three common fields show the range.

01 / LIGHT & ELECTRONICS

Photoconductive technology

Grey selenium changes conductivity when exposed to light. Its semiconductor properties have been used in photocells, rectifiers and traditional copying systems.

02 / GLASS & CERAMICS

Control color

Selenium compounds can decolorize glass or produce red tones. Ceramic glazes and pigments are further established applications.

03 / METALLURGY

Modify alloys

As an additive, selenium can influence selected metal alloys. The required composition depends on the process and final product.

05 Your specification

Three details.
A clear start.

A useful material inquiry describes the intended application and its technical needs.

01

Purity

Which minimum grade is needed? Include limits for relevant impurities.

02

Form

Do you need powder, granules or another form? Include desired dimensions.

03

Quantity

Share expected demand, timing and any repeat orders.

07 Product data

Further technical details.

Product name: selenium selenium

Atomic number
Atomic mass
Density, kg/m3
Melting point, °C  
Boiling point, °C
Heat capacity, kJ/(kg·°C)
Electronegation
Covalent radius, Å
1st ionizatz. potential

34
78,96
4790
217
685
0,352
2,5
1,16
9,75
Selenium, Se, chemical element VI of the Mendeleev periodic system; atomic number 34, atomic mass 78, 96; predominantly non-metal. Natural selenium is a mixture of six stable isotopes - 74Se (0.87%), 76Se (9.01%), 77Se (7.58%), 78Se (23.52%), 80Se (49.82%), 82Se (9.19%). Of the radioactive isotopes, 75Se is the most important with a half-life of 121 days. The element was discovered in 1817 by I. Berzelius (the name is given from the Greek selene - the moon).

Selenium distribution in nature. Selenium is a very rare and scattered element, its content in the earth's crust (clark) is 5×10-6% by mass. The history of Selene in the Earth’s crust is closely related to the history of sulfur. Selenium has the ability to concentrate and, despite its low clark, forms 38 independent minerals - natural selenides, selenites, selenates and others. Characterized isomorphic impurities of selenium in sulfides and native sulfur.

Application

The main consumers of selenium are electronics, ceramics and dyes, and the steel industry.

Electronics
For electronics, selenium is made of plates of electric rectifiers, xerographic plates, photocells, solar panels and television cameras. In all cases, selenium is required with a degree of purity of 99.99-99.999%.
Selenium straighteners. The dry selenium rectifier consists of a sandblasted substrate or an etched iron or aluminum plate coated with nickel or a thin bismuth layer and a 0.50-0.75 mm thick selenium layer. The selenium layer is applied by evaporation in a vacuum chamber or first coated with selenium powder, which is then compressed for several minutes under a hydraulic press with heated plates. The resulting "sandwich" is subjected to heat treatment for 30 minutes at a temperature slightly above 210 *. Then create an artificial barrier to increase the resistance of the device when the current passes in the opposite direction. Finally, a balancing electrode is installed from the By alloy of another metal and a selenium rectifier is included in the electrical circuit to bring and improve the locking resistance. The discs are collected in industrial appliances, which are immersed in insulating varnish and packaged for shipment.

Glass and ceramic industry

07 Inquiry

Selenium for
your project?

Tell us the purity, form and quantity you need.

PHONE NUMBER PROVISIONALinfo@rare-metals.net+49 30 0000 0000
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